Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirah'ty

Yoko Nakano; Fumiko Ichiyanagi; Masanobu Naito; Yonggang Yang; Michiya Fujiki

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Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirah'ty

机译：柠檬烯手性导致二烷基聚硅烷的镜像对称破坏聚集过程中的手性生成和转化

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摘要

We observed the emergence and inversion of chiroptical handedness in three chiroptically silent dialkylpolysilanes during aggregation in limonene-methanol-THF tersolvents.

机译：我们观察到在柠檬烯-甲醇-THF三元溶剂的聚集过程中三种手性沉默的二烷基聚硅烷中手性的出现和反转。

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来源
《Chemical Communications》 |2012年第53期|p.6636-6638|共3页
作者
Yoko Nakano; Fumiko Ichiyanagi; Masanobu Naito; Yonggang Yang; Michiya Fujiki;
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作者单位

Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan.;

Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan.;

Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan.;

Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou 215123, P.R. China;

Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan;

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Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirah'ty

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