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Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster

机译:通过连接八面体配体和三棱柱形金属簇构建的具有nia拓扑结构的高度多孔且坚固的离子型MOF

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摘要

Two non-interpenetrated and isomorphous MOFs with nia topology, cationic JUC-101 and anionic JUC-102, are synthesized by connecting a trigonal prismatic metal cluster with an octahedral organic ligand. JUC-101 obtains a BET surface area of 3742 m~2 g~(-1) and can absorb 4.18 wt% of H_2 at 30 atm and 77 K, while JUC-102 can absorb cationic dye molecules and release them under the triggering of ions.
机译:通过将三棱柱形金属簇与八面体有机配体连接,合成了两个具有nia拓扑结构的非互穿且同构的MOF,即阳离子JUC-101和阴离子JUC-102。 JUC-101的BET表面积为3742 m〜2 g〜(-1),在30 atm和77 K下可以吸收4.18 wt%的H_2,而JUC-102在阳离子交换的触发下可以吸收并释放阳离子染料分子。离子。

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  • 来源
    《Chemical Communications》 |2012年第48期|p.6010-6012|共3页
  • 作者单位

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;

    State Key laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;

    State Key laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;

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  • 入库时间 2022-08-17 13:20:51

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