Oximate metal complexes breaking the limiting esterolytic reactivity of oximate anions

Paola Gomez-Tagle; Jose Carlos Lugo-Gonzalez; Anatoly K. Yatsimirsky

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Oximate metal complexes breaking the limiting esterolytic reactivity of oximate anions

机译：含氧金属配合物破坏了肟酸阴离子的极限酯解反应性

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Zinc(Ⅱ) and cadmium(Ⅱ) complexes of a tridentate oximate ligand cleave 4-nitrophenyl acetate with rate constants surpassing by two orders of magnitude those reported as the maximum possible level for highly basic free oximate anions as a result of removal of the "solvational imbalance" of the nucleophile by metal coordination.

机译：三齿肟酸配体的锌（Ⅱ）和镉（Ⅱ）络合物裂解乙酸4-硝基苯酯，其速率常数超过报告的两个数量级，这是由于除去了“金属配位的亲核试剂的“溶剂不平衡”。

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《Chemical Communications》 |2013年第70期|7717-7719|共3页
作者
Paola Gomez-Tagle; Jose Carlos Lugo-Gonzalez; Anatoly K. Yatsimirsky;
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Universidad National Autonoma de Mexico, Facultad de Quimica, 04510, Mexico City, Mexico;

Universidad National Autonoma de Mexico, Facultad de Quimica, 04510, Mexico City, Mexico;

Universidad National Autonoma de Mexico, Facultad de Quimica, 04510, Mexico City, Mexico;

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入库时间 2022-08-17 13:18:38

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8. Probes of Nonreactive Environment. IV. 1-Methyl-4-Cyanoformylpyridinium Oximate [R] . Mackray, R. A., Poziomek, E. J. 1972

机译：非反应环境探测。 IV。 1-甲基-4-氰基甲酰基吡啶鎓氧化物

Oximate metal complexes breaking the limiting esterolytic reactivity of oximate anions

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