Ionic conductivity of [Li~+@C_(60)](PF_6~- ) in organic solvents and its electrochemical reduction to Li~+@C_(60)~(·-)

Hiroshi Ueno; Ken Kokubo; Yuji Nakamura; Kei Ohkubo; Naohiko lkuma; Hiroshi Moriyama; Shunichi Fukuzumi; Takumi Oshima

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Ionic conductivity of [Li~+@C_(60)](PF_6~- ) in organic solvents and its electrochemical reduction to Li~+@C_(60)~(·-)

机译：[Li〜+ @ C_（60）〜（PF_6〜-）在有机溶剂中的离子电导率及其电化学还原为Li〜+ @ C_（60）〜（·-）

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The ionic conductivity of [Li~+@C_(60)](PF_6~- ) was measured in o-dichlorobenzene, and found to be higher than that of TBA~+PF_6~-. Electrochemical reduction of [Li~+@C_(60)](PF_6~-) without any supporting electrolyte gave the monovalent radical anion Li~+@C_(60)~(·-), as confirmed by the characteristic ESR signal and NIR absorption band.

机译：在邻二氯苯中测定了[Li〜+ @ C_（60）]（PF_6〜-）的离子电导率，发现其高于TBA〜+ PF_6〜-。由特征ESR信号和NIR证实，在没有任何支持电解质的情况下，电化学还原[Li〜+ @ C_（60）]（PF_6〜-）得到一价基团阴离子Li〜+ @ C_（60）〜（·-）。吸收带。

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来源
《Chemical Communications》 |2013年第67期|7376-7378|共3页
作者
Hiroshi Ueno; Ken Kokubo; Yuji Nakamura; Kei Ohkubo; Naohiko lkuma; Hiroshi Moriyama; Shunichi Fukuzumi; Takumi Oshima;
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Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan;

Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan;

Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan;

Department of Material and Life Science, Graduate School of Engineering, Osaka University, and ALCA, Japan Science and Technology (JST), Suita, Osaka 565-0871, Japan;

Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan;

Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan;

Department of Material and Life Science, Graduate School of Engineering, Osaka University, and ALCA, Japan Science and Technology (JST), Suita, Osaka 565-0871, Japan , Department of Bioinspired Science, Ewha Womans University, Seoul;

Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan;

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1. EPR Studies Associated with the Electrochemical Reduction of C_(60) and Supramolecular Complexes of C_(60) in Toluene-Acetonitrile Solvent Mixtures [J] . Scott A. Olsen, Alan M. Bond, Richard G. Compton, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第16期

机译：EPR研究与C_（60）和C_（60）的超分子配合物在甲苯-乙腈溶剂混合物中的电化学还原
2. Electrochemical behavior of C_(60) films and C_(60)/lipid films in ionic liquids [J] . Yi Li, Hongguang Li, Xiangfeng Jia Carbon: An International Journal Sponsored by the American Carbon Society . 2006,第5期

机译：C_（60）膜和C_（60）/脂质膜在离子液体中的电化学行为
3. Darstellung und Charakterisierung der Fulleren-Kokristallisate C_(60) · 12C_6H_(12), C_(70) · 12C_6H_(12), C_(60) · 12CCl_4, C_(60) · 2CHBr_3, C_(60) · 2CHCl_3, C_(60) · 2H_2CCl_2 [J] . M. Jansen, G. Waidmann Zeitschrift fur Anorganische und Allgemeine Chemie . 1995,第1期

机译：富勒烯共结晶物C_（60）12C_6H_（12），C_（70）12C_6H_（12），C_（60）12CCl_4，C_（60）2CHBr_3，C_（60）2CHCl_3，C_（ 60）2H_2CCl_2
4. Photoelectron spectroscopy of the Li~+@C_(60)PF_6~- salt and STM of the single Li~+@C_(60) molecules on Cu(111) [C] . C. Zhang, A. V. Kuklin, F. Esaka, 2018年第79回応用物理学会秋季学術講演会講演予稿集 . 2018

机译：Li〜+ @ C_（60）PF_6〜-盐的光电子能谱和Cu（111）上单个Li〜+ @ C_（60）分子的STM
5. Polar ionic media and stabilized charged species in organic synthesis: Ionic liquids derived from a biorenewable source, D-fructose, as a possible alternative to conventional organic reaction solvents. [D] . Okello, Maurice O. 2004

机译：有机合成中的极性离子介质和稳定的带电物种：来源于生物可再生来源D-果糖的离子液体，可以作为常规有机反应溶剂的替代方法。
6. Electrochemical reduction of cationic Li+@C60 to neutral Li+@C60˙–: isolation and characterisation of endohedral 60fulleride [O] . Hiroshi Ueno, Shinobu Aoyagi, Yu Yamazaki, 2016

机译：电化学将阳离子Li + @ C60还原为中性Li + @ C60˙–：内面60富勒利德的分离和表征
7. Formations of Dumbbell C_{118} and C_{119} inside Clusters of C_{60} Molecules by Collision with α Particles [O] . Zettergren, H., Rousseau, P., Wang, Y., 2013

机译：与α粒子碰撞在C_ {60}分子簇内形成哑铃C_ {118}和C_ {119}

Ionic conductivity of [Li~+@C_(60)](PF_6~- ) in organic solvents and its electrochemical reduction to Li~+@C_(60)~(·-)

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