Reaction of strongly electrophilk alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions

Olga Ekkert; Ottmar Tuschewitzki; Constantin G. Daniliuc; Gerald Kehr; Gerhard Erker

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Reaction of strongly electrophilk alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions

机译：强亲电性烯基硼烷与膦基炔烃的反应：分子间1,1-烯基硼化反应的罕见例子

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摘要

Simple alkenylbis(pentafluorophenyl)boranes undergo 1,1-alkenylboration with phosphanylacetylenes to give phosphane-borane Lewis pairs with a conjugated diene backbone.

机译：简单的烯基双（五氟苯基）硼烷与膦基乙炔进行1,1-烯基硼酸酯化反应，生成具有共轭二烯骨架的膦-硼烷路易斯对。

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《Chemical Communications》 |2013年第62期|6992-6994|共3页
作者
Olga Ekkert; Ottmar Tuschewitzki; Constantin G. Daniliuc; Gerald Kehr; Gerhard Erker;
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Organisch-Chemisches Institut, Universitat Muenster, Corrensstrasse 40, D-48149 Muenster, Germany;

Organisch-Chemisches Institut, Universitat Muenster, Corrensstrasse 40, D-48149 Muenster, Germany;

Organisch-Chemisches Institut, Universitat Muenster, Corrensstrasse 40, D-48149 Muenster, Germany;

Organisch-Chemisches Institut, Universitat Muenster, Corrensstrasse 40, D-48149 Muenster, Germany;

Organisch-Chemisches Institut, Universitat Muenster, Corrensstrasse 40, D-48149 Muenster, Germany;

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Reaction of strongly electrophilk alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions

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