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J- vs. H-type assembly: pentamethine cyanine (Cy5) as a near-IR chiroptical reporter

机译:J型和H型装配:五甲花青(Cy5)作为近红外整脊报告基因

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摘要

The DNA-enabled dimerization of pentamethine cyanine (Cy5) dyes was studied by optical methods. The value of cyanine as a chiroptical reporter using a monomer-to-dimer switch is demonstrated. The specific shape of the CD signal and its high intensity are a result of J-type assembly.
机译:通过光学方法研究了五甲胺花青(Cy5)染料的DNA致二聚作用。证明了花青作为使用单体-二聚体开关的手性报告分子的价值。 CD信号的特定形状及其高强度是J型装配的结果。

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  • 来源
    《Chemical Communications》 |2013年第46期|5298-5300|共3页
  • 作者单位

    Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3,CH-3012 Bern, Switzerland,Department of Organic Luminophores and Dyes, 'Institute for Single Crystals',Nat Acad. Sci. Ukraine, 60, Lenin Ave., Kharkiv 61001, Ukraine;

    Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3,CH-3012 Bern, Switzerland;

    Department of Organic Luminophores and Dyes, 'Institute for Single Crystals',Nat Acad. Sci. Ukraine, 60, Lenin Ave., Kharkiv 61001, Ukraine;

    Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3,CH-3012 Bern, Switzerland;

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  • 入库时间 2022-08-17 13:18:24

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