Carbolithiation of meso-aryl-substituted 5,15-diazaporphyrin selectively provides 3-alkylated diazachlorins

Ayaka Yamaji; Satoru Hiroto; Ji-Young Shin; Hiroshi Shinokubo

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Carbolithiation of meso-aryl-substituted 5,15-diazaporphyrin selectively provides 3-alkylated diazachlorins

机译：介孔芳基取代的5,15-二氮杂卟啉的羰基化选择性地提供3-烷基化的二氮杂绿素

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Treatment of meso-mesityl 5,15-diazaporphyrin with alkyllithiums in toluene at low temperature provided monoalkylated diazachlorins through highly regioselective nucleophilic addition at the β-position near the meso-nitrogen atom.

机译：在低温下用烷基锂在甲苯中处理间苯二甲酰基5,15-二氮杂卟啉，通过在中氮原子附近的β位上进行高度区域选择性的亲核加成反应，提供了单烷基化的二氮杂ins呤。

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《Chemical Communications》 |2013年第44期|5064-5066|共3页
作者
Ayaka Yamaji; Satoru Hiroto; Ji-Young Shin; Hiroshi Shinokubo;
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Department of Applied Chemistry, Grqduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan;

Department of Applied Chemistry, Grqduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan;

Department of Applied Chemistry, Grqduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan;

Department of Applied Chemistry, Grqduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan;

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入库时间 2022-08-17 13:18:23

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1. Direct and Regioselective Amination of -Unsubstituted 5,15-Diazaporphyrins with Amines: A Convenient Route to Near-Infrared-Responsive Diazaporphyrin Sensitizers [J] . Omomo Satoshi, Sugai Takuma, Minoura Mao, Angewandte Chemie . 2018,第14期

机译：与胺的直接和区域选择性 - 单独的5,15-二氮杂肾上腺素 - 近红外响应二氮杂肾上腺素敏化剂的便利途径
2. Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N-Alkyl Groups [J] . Mutoh Mai, Sudoh Keisuke, Furukawa Ko, Asian Journal of Organic Chemistry . 2019,第3期

机译：氧化还原5,15-二烷基-10,20-二芳基-5,15-二氮杂物的合成及其正烷基的多样化
3. Synthesis and optical, magnetic, and electrochemical properties of 5,10,15,20-tetraaryl-5,15-diazaporphyrin - tertiary amine conjugates [J] . Journal of porphyrins and phthalocyanines . 2020,第1a3期

机译：合成和光学，磁性和电化学性能为5,10,15,20-四芳基-5,15-二氮杂素 - 叔胺缀合物
4. Synthesis and properties of N-methyl-5,15-diazaporphyrin [C] . Chia Wen Xi, Tsubasa Nishimura, Hiroto Omori 日本化学会春季年会講演予稿集 . 2018

机译：N-甲基-5,15-二氮素卟啉的合成与性质
5. Selective meso-monobromination of 5,15-diarylporphyrins via organopalladium porphyrins [O] . Aiko Katoa, Regan D. Hartnella, Masahiro Yamashitab, 2015

机译：有机钯卟啉对5,15-二芳基卟啉的选择性内消旋单溴化反应

Carbolithiation of meso-aryl-substituted 5,15-diazaporphyrin selectively provides 3-alkylated diazachlorins

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