Carborane tuning of photophysical properties of phosphorescent iridium(Ⅲ) complexes

Chao Shi; Huibin Sun; Qibai Jiang; Qiang Zhao; Jingxia Wang; Wei Huang; Hong Yan

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Carborane tuning of photophysical properties of phosphorescent iridium(Ⅲ) complexes

机译：碳硼烷调节磷光铱（Ⅲ）配合物的光物理性质

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Both neutral and cationk iridium(Ⅲ) complexes containing carborane units were synthesized. Bulky carboranes can significantly improve phosphorescence quantum yields of these complexes and the electronic effect of carboranes can evidently tune emission wavelengths of cationic complexes.

机译：合成了具有碳硼烷单元的中性和阳离子铱（Ⅲ）配合物。庞大的碳硼烷可以显着提高这些配合物的磷光量子产率，并且碳硼烷的电子效应可以明显地调节阳离子配合物的发射波长。

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《Chemical Communications》 |2013年第42期|4746-4748|共3页
作者
Chao Shi; Huibin Sun; Qibai Jiang; Qiang Zhao; Jingxia Wang; Wei Huang; Hong Yan;
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作者单位

State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China;

Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, P. R. China;

State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China;

Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, P. R. China;

Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, P. R. China;

Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, P. R. China;

State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China;

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1. Variable Photophysical Properties of Phosphorescent Iridium(III) Complexes Triggered by closo-and nido-Carborane Substitution [J] . Chao Shi, Huibin Sun, Xiao Tang Angewandte Chemie . 2013,第50期

机译：closo和nido-Carborane取代引发的磷铱（III）配合物的可变光物理性质
2. Tuning the Photophysical and Excited State Properties of Phosphorescent Iridium(III) Complexes by Polycyclic Unit Substitution [J] . Cuicui Wu, Qiuxia Li, Xinghua Zhang, ChemistryOpen . 2019,第3期

机译：通过多环单元取代调节磷光铱（III）配合物的光物理和激发态性质
3. Highly efficient phosphorescent iridium (III) diazine complexes for OLEDs: Different photophysical property between iridium (III) pyrazine complex and iridium (III) pyrimidine complex [J] . Ge GP, He J, Guo HQ, Journal of Organometallic Chemistry . 2009,第19期

机译：用于OLED的高效磷光铱（III）二嗪配合物：铱（III）吡嗪配合物和铱（III）嘧啶配合物的光物理性质不同
4. Luminescent iridium(III) polypyridine PEG complexes: Synthesis, photophysical, and biological properties [C] . Li Steve Po-Yam, Tsai Johnson Lui-Lui, Lo Kenneth Kam-Wing Proceedings of the IEEE 4th International Conference on Nano/Molecular Medicine and Engineering . 2010

机译：发光铱（III）聚吡啶PEG复合物：合成，光物理和生物学性质
5. Synthesis and photophysical characterization of phosphorescent cyclometalated iridium(III) complexes and their use in organic light emitting devices. [D] . Sajoto, Tissa. 2008

机译：磷光环金属化铱（III）配合物的合成和光物理表征及其在有机发光器件中的用途。
6. Tuning the Photophysical and Excited State Properties of Phosphorescent Iridium(III) Complexes by Polycyclic Unit Substitution [O] . Cuicui Wu, Qiuxia Li, Xinghua Zhang, 2019

机译：通过多环单元取代调节磷光铱（III）配合物的光物理和激发态性质
7. Strongly Phosphorescent Iridium(III)–Porphyrins – New Oxygen Indicators with Tuneable Photophysical Properties and Functionalities [O] . Koren, Klaus, Borisov, Sergey M, Saf, Robert, 2011

机译：强磷铱（III）-卟啉-具有可调节光物理性质和功能的新型氧指示剂

Carborane tuning of photophysical properties of phosphorescent iridium(Ⅲ) complexes

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