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Cu(II)-catalyzed decarboxylative acylation of acyl C-H of formamides with α-oxocarboxylic acids leading to a-ketoamides

机译:Cu(II)催化的甲酰胺酰基C-H与α-氧代羧酸的脱羧酰化反应,生成α-酮酰胺

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摘要

CuBr_2-catalyzed decarboxyiative acylation of the acyl C-H of N-monosubstituted and N,N-disubstituted formamides with α-oxocarboxylic acids leading to α-ketoamides was developed, which generated the corresponding products in good yields.
机译:研究了CuBr_2催化的N-单取代和N,N-二取代甲酰胺的酰基C-H与α-氧代羧酸生成α-酮酰胺的脱羧酰化反应,得到了相应的产物,收率很高。

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  • 来源
    《Chemical Communications》 |2013年第35期|3640-3642|共3页
  • 作者单位

    Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000,P. R. China;

    Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000,P. R. China;

    Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000,P. R. China;

    Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000,P. R. China;

    Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000,P. R. China State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China;

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