Conformationally restricted pyrrolidines by intramolecular [2+2] photocycloaddition reactions

Diego A. Fort; Thomas J. Woltering; Matthias Nettekoven; Henner Knust; Thorsten Bach

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Conformationally restricted pyrrolidines by intramolecular [2+2] photocycloaddition reactions

机译：分子内[2 + 2]光环加成反应构象受限的吡咯烷

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Intramolecular [2+2] photocycloaddition reactions of diversely substituted N-Boc protected 4-(allylaminomethyl)-2(5H)-furanones resulted in rigid products (53-75%) with three spatially defined positions for further functionalisation.

机译：不同取代的N-Boc保护的4-（烯丙基氨基甲基）-2（5H）-呋喃酮的分子内[2 + 2]光环加成反应产生具有三个空间确定位置的硬产物（53-75％），用于进一步官能化。

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《Chemical Communications》 |2013年第29期|2989-2991|共3页
作者
Diego A. Fort; Thomas J. Woltering; Matthias Nettekoven; Henner Knust; Thorsten Bach;
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Lehrstuhl fuer Organische Chemie I, Technische Universitaet Muenchen, 85747 Garching, Germany;

Discovery Chemistry, PRCB, F. Hoffmann-La Roche AG, Grenzacherstrasse 124, 4070 Basel, Switzerland;

Discovery Chemistry, PRCB, F. Hoffmann-La Roche AG, Grenzacherstrasse 124, 4070 Basel, Switzerland;

Discovery Chemistry, PRCB, F. Hoffmann-La Roche AG, Grenzacherstrasse 124, 4070 Basel, Switzerland;

Lehrstuhl fuer Organische Chemie I, Technische Universitaet Muenchen, 85747 Garching, Germany;

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1. An Intramolecular [2 + 2] Photocycloaddition Approach to Conformationally Restricted Bis-Pyrrolidines [J] . Diego A. Fort, Thomas J. Woltering, Andre?M. Alker, The Journal of Organic Chemistry . 2014,第15期

机译：分子内[2 + 2]光环加成法构象受限的双吡咯烷。
2. An Intramolecular [2 + 2] Photocycloaddition Approach to Conformationally Restricted Bis-Pyrrolidines [J] . Diego A. Fort, Thomas J. Woltering, Andre?M. Alker, The Journal of Organic Chemistry . 2014,第15期

机译：分子内[2 + 2]光环加成法构象受限的双吡咯烷。
3. SYNTHESIS AND INTRAMOLECULAR PHOTOCYCLOADDITIONS OF 2-ACYLOXY-3-HEXENOYL CYCLOHEXENONES - DIASTEREOSELECTIVITY IN THE INTRAMOLECULAR [2+2] PHOTOCYCLOADDITIONS OF ALKENES AND CYCLOHEXENONES TETHERED BY FOUR ATOMS [J] . Crimmins MT., Watson PS., Guise LE., Tetrahedron . 1997,第26期

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4. Side chain-to-Side chain Cyclization by Intramolecular Click Reaction - Building Blocks, Solid Phase Synthesis and Conformational Characterization [C] . Soma Cantel, Jose A. Halperin, Michael Chorev American Peptide Symposium . 2009

机译：侧链到侧链通过分子内咔哒反应 - 构建块，固相合成和构象表征
5. A general strategy for stereochemical control of enone-olefin [2+2]-photocycloaddition reactions and application of SET-promoted photocyclization to the synthesis of cyclic peptide analogs. [D] . Cai, Xiaolu. 2003

机译：立体化学控制烯-烯烃[2 + 2]-光环加成反应的一般策略，以及SET促进的光环化在环肽类似物合成中的应用。
6. Intramolecular 2+2 Photocycloaddition of Cyclic Enones: Selectivity Control by Lewis Acids and Mechanistic Implications [O] . Saner Poplata, Dr. Andreas Bauer, Dr. Golo Storch, -1

机译：环状烯酮的分子内2 + 2光环加成：路易斯酸的选择性控制及其机理意义
7. Conformational Analysis in Reversible Intramolecular 2+2 Photocycloaddition of Diphenylbicyclo4.2.0oct-3-ene-2,5-diones [O] . Asahara Haruyasu, Mochizuki Eiko, Oshima Takumi 2006

机译：二苯基双环4.2.0 oct-3-ene-2,5-diones可逆分子内2 + 2光环加成反应的构象分析
8. The Temperature Dependence of Triplet State Reaction Rate and Quantum Yield for an Intramolecular Enone Photocycloaddition. [R] . jones, guilford ii ramachandran, bellampalli r. 1976

机译：分子内烯酮光环加成反应的三重态反应速率和量子产率的温度依赖性。

Conformationally restricted pyrrolidines by intramolecular [2+2] photocycloaddition reactions

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