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首页> 外文期刊>Chemical Communications >Unusual conformational preference of an aromatic secondary urea: solvent-dependent open-closed conformational switching of N,N'-bis(porphyrinyl)ureat
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Unusual conformational preference of an aromatic secondary urea: solvent-dependent open-closed conformational switching of N,N'-bis(porphyrinyl)ureat

机译：芳香族二级脲的异常构象偏爱：N，N'-双（卟啉基）脲的溶剂依赖性开闭构象转换

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摘要

N,N''-Bis(2,3,7,8,12,13,17,18-octaethylporphyrin-5-yl)urea (3) exhibits cis-trans conformational switching depending on the solvent properties, and can adopt the cofacial porphyrin dimer structure under certain conditions. The conformational preference can be switched by electrochemical stimulus.
机译：N，N''-Bis（2,3,7,8,12,13,17,18-八乙基卟啉-5-基）脲（3）根据溶剂性质表现出顺反构象转换，可以采用一定条件下的表面卟啉二聚体结构。构象偏好可以通过电化学刺激来切换。

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  • 来源
    《Chemical Communications》 |2013年第23期|2290-2292|共3页
  • 作者

    Mio Matsumura; Aya Tanatani; Isao Azumaya; Hyuma Masu; Daisuke Hashizume; Hiroyuki Kagechika; Atsuya Muranaka; Masanobu Uchiyama;

  • 作者单位

    Department of Chemistry, Faculty of Science, Ochanomizu University, 2-1-1 Otsuka, Bunkyo-ku, Tokyo 112-8610, Japan;

    Department of Chemistry, Faculty of Science, Ochanomizu University, 2-1-1 Otsuka, Bunkyo-ku, Tokyo 112-8610, Japan;

    Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, 1314-1 Shido, Sanuki, Kagawa 769-2193, Japan;

    Chemical Analysis Center, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan;

    Advanced Technology Support Division and Advanced Elements Chemistry Research Team, RIKEN-ASI, 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan;

    Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University, 2-3-10 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-0062, Japan;

    Advanced Technology Support Division and Advanced Elements Chemistry Research Team, RIKEN-ASI, 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan;

    Advanced Technology Support Division and Advanced Elements Chemistry Research Team, RIKEN-ASI, 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan,Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan;

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  • 入库时间 2022-08-17 13:18:01

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