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Squaramide-based tripodal receptors for selective recognition of sulfate anion

机译:基于Squaramide的三脚架受体,可选择性识别硫酸根阴离子

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摘要

Squaramide-based tripodal anion receptors 1-3 have been prepared and their anion binding properties with various inorganic anions were investigated. Receptor 1 formed a dimeric complex in solid state and a 1∶1 complex in solution with SO_4~(2-). All receptors 1-3 could selectively encapsulate SO_4~(2-) via hydrogen bonds over other examined anions.
机译:制备了基于方酰胺的三脚架阴离子受体1-3,并研究了它们与各种无机阴离子的阴离子结合性能。受体1与SO_4〜(2-)形成固态的二聚体复合物,与溶液形成1∶1的复合物。所有受体1-3都可以通过氢键选择性地包封SO_4〜(2-),而不影响其他阴离子。

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  • 来源
    《Chemical Communications》 |2013年第20期|2025-2027|共3页
  • 作者单位

    Center for Multimolecular Chemistry, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University,Nanjing210093, China;

    Center for Multimolecular Chemistry, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University,Nanjing210093, China;

    Center for Multimolecular Chemistry, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University,Nanjing210093, China;

    Center for Multimolecular Chemistry, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University,Nanjing210093, China;

    Center for Multimolecular Chemistry, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University,Nanjing210093, China;

    Center for Multimolecular Chemistry, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University,Nanjing210093, China;

    Center for Multimolecular Chemistry, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University,Nanjing210093, China;

    Center for Multimolecular Chemistry, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University,Nanjing210093, China;

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