Boryl-assisted hydrogenolysis of a nickel-methyl bond

Natalia Curado; Celia Maya; Joaquin Lopez-Serrano; Amor Rodriguez

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Boryl-assisted hydrogenolysis of a nickel-methyl bond

机译：硼基辅助的镍-甲基键氢解

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A stable nickel(Ⅱ) methyl complex containing a diphosphino-boryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond suggest a metal ligand cooperation mechanism that involves the intermediacy of a σ-B-H Ni(0) species that further undergoes B-H oxidative addition to form a Ni(Ⅱ) hydride complex.

机译：描述了一种稳定的含二膦基硼基（PBP）钳位配体的镍（Ⅱ）甲基配合物。 Ni-Me键的氢解机理研究表明，金属配体的协同作用机制涉及σ-B-HNi（0）物种的中介，该物种进一步经过B-H氧化加成形成Ni（Ⅱ）氢化物络合物。

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《Chemical Communications》 |2014年第99期|15718-15721|共4页
作者
Natalia Curado; Celia Maya; Joaquin Lopez-Serrano; Amor Rodriguez;
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作者单位

Instituto de Investigaciones Quimicas-Departamento de Quimica Inorganica, Centro de Innovacion en Quimica Avanzada (ORFEO-CINQA), Universidad de Sevilla-Consejo Superior de Investigaciones Cientificas, Avenida Americo Vespucio 49, 41092 Sevilla, Spain;

Instituto de Investigaciones Quimicas-Departamento de Quimica Inorganica, Centro de Innovacion en Quimica Avanzada (ORFEO-CINQA), Universidad de Sevilla-Consejo Superior de Investigaciones Cientificas, Avenida Americo Vespucio 49, 41092 Sevilla, Spain;

Instituto de Investigaciones Quimicas-Departamento de Quimica Inorganica, Centro de Innovacion en Quimica Avanzada (ORFEO-CINQA), Universidad de Sevilla-Consejo Superior de Investigaciones Cientificas, Avenida Americo Vespucio 49, 41092 Sevilla, Spain;

Instituto de Investigaciones Quimicas-Departamento de Quimica Inorganica, Centro de Innovacion en Quimica Avanzada (ORFEO-CINQA), Universidad de Sevilla-Consejo Superior de Investigaciones Cientificas, Avenida Americo Vespucio 49, 41092 Sevilla, Spain;

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入库时间 2022-08-17 13:16:46

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7. Boryl-assisted hydrogenolysis of a nickel–methyl bond [O] . Curado, Natalia, Maya, Celia, López-Serrano, Joaquín, 2014

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Boryl-assisted hydrogenolysis of a nickel-methyl bond

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