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The solvent effect in an axially symmetric Fe~Ⅲ_4 single-molecule magnet

机译：轴对称Fe〜Ⅲ_4单分子磁体的溶剂效应

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摘要

A pair of enantiopure Fe~Ⅲ_4 SMMs with axial symmetry was synthesized and characterized by magnetization and high-frequency electron paramagnetic resonance methods. The results reveal that the axial symmetry of the structure is broken by the interaction of Fe~Ⅲ_4 with the disordered solvent molecules.
机译：合成了一对轴向对称的对映纯Fe〜Ⅲ_4SMM，并利用磁化和高频电子顺磁共振方法对其进行了表征。结果表明，Fe〜Ⅲ_4与无序溶剂分子的相互作用破坏了结构的轴对称性。

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  • 来源
    《Chemical Communications》 |2014年第95期|15090-15093|共4页
  • 作者

    Yuan-Yuan Zhu; Ting-Ting Yin; Shang-Da Jiang; Anne-Laure Barra; Wolfgang Wernsdorfer; Petr Neugebauer; Raphael Marx; Maria Doerfel; Bing-Wu Wang; Zong-Quan Wu; Joris van Slageren; Song Gao;

  • 作者单位

    Key Laboratory of Advanced Functional Materials and Devices, Anhui Province, School of Chemical Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China ,Beijing National Laboratory of Molecular Science, College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, 100871, P. R. China;

    Key Laboratory of Advanced Functional Materials and Devices, Anhui Province, School of Chemical Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China;

    1. Physikalisches Institut, Universitaet Stuttgart, Pfaffenwaldring 57, 70569 Stuttgart, Germany ,LNCMI-CNRS, 25 rue des Martyrs BP 166, 38042 Grenoble Cedex 9, France;

    LNCMI-CNRS, 25 rue des Martyrs BP 166, 38042 Grenoble Cedex 9, France;

    Institut Neel, CNRS & UJF BP 166, 38042, Grenoble Cedex 9, France;

    Institut fuer Physikalische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany;

    Institut fuer Physikalische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany;

    Institut fuer Physikalische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany;

    Beijing National Laboratory of Molecular Science, College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, 100871, P. R. China;

    Key Laboratory of Advanced Functional Materials and Devices, Anhui Province, School of Chemical Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China;

    Institut fuer Physikalische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany;

    Beijing National Laboratory of Molecular Science, College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, 100871, P. R. China;

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  • 入库时间 2022-08-17 13:16:43

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