Reactivity of a Ru(Ⅲ)-hydroxo complex in substrate oxidation in water

Shingo Ohzu; Tomoya Ishizuka; Hiroaki Kotani; Takahiko Kojima

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Reactivity of a Ru(Ⅲ)-hydroxo complex in substrate oxidation in water

机译：Ru（Ⅲ）-羟基配合物在水中底物氧化中的反应性

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A mononuclear Ru~Ⅲ-OH complex oxidizes substrates such as hydro-quinones in water through a pre-equilibrium process based on adduct formation by hydrogen bonding between the Ru~Ⅲ-OH complex and the substrates. The reaction mechanism switches from hydrogen atom transfer to electron transfer depending on the oxidation potential of substrates.

机译：单核Ru〜Ⅲ-OH配合物通过基于Ru〜Ⅲ-OH配合物与底物之间氢键形成加合物的预平衡过程，通过预平衡过程氧化水中的氢醌等底物。反应机理根据底物的氧化电势从氢原子转移转换为电子转移。

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来源
《Chemical Communications》 |2014年第95期|15018-15021|共4页
作者
Shingo Ohzu; Tomoya Ishizuka; Hiroaki Kotani; Takahiko Kojima;
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作者单位

Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsu.ku.ba, Ibaraki 305-8571, Japan;

Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsu.ku.ba, Ibaraki 305-8571, Japan;

Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsu.ku.ba, Ibaraki 305-8571, Japan;

Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsu.ku.ba, Ibaraki 305-8571, Japan;

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入库时间 2022-08-17 13:16:40

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Reactivity of a Ru(Ⅲ)-hydroxo complex in substrate oxidation in water

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