Mn(Ⅲ)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines

Jia-Jia Cao; Xiang Wang; Shun-Yi Wang; Shun-Jun Ji

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Mn(Ⅲ)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines

机译：Mn（Ⅲ）介导的2-异氰基联芳与1,3-二羰基化合物的反应：6-烷基化和6-单氟烷基化菲啶的有效合成

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摘要

Mn(Ⅲ)-mediated reactions of 2-isocyanobiaryls with 1,3-dicarbonyl compounds were described for the construction of 6-alkylated and 6-monofluoro-alkylated phenanthridines in moderate to good yields. The reaction involves formation of two new C-C bonds and one C-C bond cleavage.

机译：用Mn（Ⅲ）介导的2-异氰基联芳基与1，3-二羰基化合物的反应以中等至良好的产率构建6-烷基化和6-单氟烷基化的菲啶。该反应涉及形成两个新的C-C键和一个C-C键裂解。

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《Chemical Communications》 |2014年第85期|12892-12895|共4页
作者
Jia-Jia Cao; Xiang Wang; Shun-Yi Wang; Shun-Jun Ji;
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Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

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Mn(Ⅲ)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines

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