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首页> 外文期刊>Chemical Communications >Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc_3N@/_h-C_(80) affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes
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Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc_3N@/_h-C_(80) affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes

机译:高苯基区域选择性地将二苯基硝胺亚胺1,3-偶极环加成到Sc_3N @ / _ h-C_(80),提供了非常稳定,前所未有的内表面金属富勒烯的吡唑环稠合衍生物

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摘要

Formation of a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes was achieved by the first 1,3-dipolar cycloaddition reaction of Sc_3N@C_(80) with diphenylnitrilimine in a highly regioselective manner.
机译:通过Sc_3N @ C_(80)的第一个1,3-偶极环加成反应与二苯基硝苯胺以高度区域选择性的方式实现了内表面金属富勒烯的非常稳定,前所未有的吡唑环稠合衍生物的形成。

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  • 来源
    《Chemical Communications》 |2014年第84期|12710-12713|共4页
  • 作者单位

    Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education, Hunan Province College Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China;

    Lab for New Fiber Materials and Modern Textile-Growing Base for State Key Laboratory, College of Chemical and Environmental Engineering, Qingdao University, Qingdao, 266071, China;

    Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education, Hunan Province College Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China;

    Lab for New Fiber Materials and Modern Textile-Growing Base for State Key Laboratory, College of Chemical and Environmental Engineering, Qingdao University, Qingdao, 266071, China;

    State Key Laboratory of Materials Processing and Die & Mold Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China;

    State Key Laboratory of Materials Processing and Die & Mold Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China;

    State Key Laboratory of Materials Processing and Die & Mold Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China;

    State Key Laboratory of Materials Processing and Die & Mold Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China;

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