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Porous organic ligands (POLs) for synthesizing highly efficient heterogeneous catalysts

机译：用于合成高效多相催化剂的多孔有机配体（POL）

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摘要

We reported a universal route for synthesizing porous organic ligands (POLs) via solvothermal polymerization. The POLs were obtained quantitatively, showing high surface area, large pore volume, hierarchical porosity, and superior stability. The POL bearing a triphenyl-phosphine supported rhodium catalyst (Rh/POL-PPh_3) exhibits high activity and excellent recydability in 1-octene hydroformylation.
机译：我们报道了通过溶剂热聚合合成多孔有机配体（POL）的通用途径。定量获得POL，显示高表面积，大孔体积，分层孔隙率和出色的稳定性。带有三苯基膦负载的铑催化剂（Rh / POL-PPh_3）的POL在1-辛烯加氢甲酰化反应中表现出高活性和优异的可重复利用性。

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  • 来源
    《Chemical Communications》 |2014年第80期|11844-11847|共4页
  • 作者

    Qi Sun; Miao Jiang; Zhenju Shen; Yinying Jin; Shuxiang Pan; Liang Wang; Xiangju Meng; Wangzhi Chen; Yunjie Ding; Jixue Li; Feng-Shou Xiao;

  • 作者单位

    Department of Chemistry, Zhejiang University, Hangzhou 310028, P.R. China,Electron Microscopy Centre, Zhejiang University, Hangzhou 310027, P.R. China;

    Dalian Institute of Chemical Physics, Dalian 116023, P.R. China;

    Electron Microscopy Centre, Zhejiang University, Hangzhou 310027, P.R. China;

    Department of Chemistry, Zhejiang University, Hangzhou 310028, P.R. China;

    Department of Chemistry, Zhejiang University, Hangzhou 310028, P.R. China;

    Department of Chemistry, Zhejiang University, Hangzhou 310028, P.R. China;

    Department of Chemistry, Zhejiang University, Hangzhou 310028, P.R. China;

    Department of Chemistry, Zhejiang University, Hangzhou 310028, P.R. China;

    Dalian Institute of Chemical Physics, Dalian 116023, P.R. China;

    Electron Microscopy Centre, Zhejiang University, Hangzhou 310027, P.R. China;

    Department of Chemistry, Zhejiang University, Hangzhou 310028, P.R. China;

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  • 入库时间 2022-08-17 13:16:23

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