Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity

Wen Zhou; Brian O. Patrick; Kevin M. Smith

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Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity

机译：氧化还原非纯苯二胺配体对亚氨基铬氢原子提取反应性的影响

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Paramagnetic CpCr[(RN)_2C_6H_4] compounds (R = SiMe_3, CH_2CMe_3 and Ph) were treated with R'N_3 azides to generate chromium imido complexes, CpCr[(RN)_2C_6H_4](NR'), with R' = adamantyl, aryl or SO_2Ar. The H-atom abstraction reactivity of the imido complexes differed as the R and R' substituents were varied.

机译：用R'N_3叠氮化物处理顺磁性CpCr [（RN）_2C_6H_4]化合物（R = SiMe_3，CH_2CMe_3和Ph）生成铬酰亚胺基络合物CpCr [（RN）_2C_6H_4]（NR'），R'=金刚烷基，芳基或SO_2Ar。亚氨基配合物的氢原子抽象反应性随R和R'取代基的变化而不同。

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《Chemical Communications》 |2014年第69期|9958-9960|共3页
作者
Wen Zhou; Brian O. Patrick; Kevin M. Smith;
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Department of Chemistry, University of British Columbia Okanagan, 3333 University Way, Kelowna, BC, Canada;

Department of Chemistry, University of British Columbia, Vancouver, BC, Canada;

Department of Chemistry, University of British Columbia Okanagan, 3333 University Way, Kelowna, BC, Canada;

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入库时间 2022-08-17 13:16:11

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Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity

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