Synthesis and characterization of a new Keggin anion: [BeW_(12)O_(40)]~(6-)

Alexander V. Anyushin; Anton I. Smolentsev; Dmitry A. Mainichev; Cristian Vicent; Artem L. Gushchin; Maxim N. Sokolov; Vladimir P. Fedin

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Synthesis and characterization of a new Keggin anion: [BeW_(12)O_(40)]~(6-)

机译：一种新的Keggin阴离子的合成与表征：[BeW_（12）O_（40）]〜（6-）

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The first Keggin-type Be-containing heteropolyanion [BeW_(12)O_(40)]~(6-) (1~(6-)) has been obtained by hydrothermal synthesis from sodium tungstate and Be(NO_3)_2. It was crystallized as (Bu_4N)_(4.8)Na_(1.2)[BeW_(12)O_(40)] (1a) and (Me_2NH_2)_6[BeW_(12)O_(40)]·4H_2O (1b) salts, which were characterized by ~9Be and ~(183)W NMR, ESI-MS, CV. and single crystal X-ray diffraction analysis.

机译：通过水热合成由钨酸钠和Be（NO_3）_2获得了第一个含Keggin型Be的杂多阴离子[BeW_（12）O_（40）]〜（6-）（1〜（6-））。结晶为（Bu_4N）_（4.8）Na_（1.2）[BeW_（12）O_（40）]（1a）和（Me_2NH_2）_6 [BeW_（12）O_（40）]·4H_2O（1b）盐，通过〜9Be和〜（183）W NMR，ESI-MS，CV表征。和单晶X射线衍射分析。

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《Chemical Communications》 |2014年第65期|9083-9085|共3页
作者
Alexander V. Anyushin; Anton I. Smolentsev; Dmitry A. Mainichev; Cristian Vicent; Artem L. Gushchin; Maxim N. Sokolov; Vladimir P. Fedin;
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Nikolaev Institute of Inorganic Chemistry SB RAS, Pr. Lavrentieva 3, Novosibirsk, 630090, Russia,Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, Pr. Lavrentieva 3, Novosibirsk, 630090, Russia,Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, Pr. Lavrentieva 3, Novosibirsk, 630090, Russia;

Serveis Centrals d'Instrumentacio Cientifica, Universitat Jaume Ⅰ, Avda. Sos Baynat s, E-12071 Castello, Spain;

Nikolaev Institute of Inorganic Chemistry SB RAS, Pr. Lavrentieva 3, Novosibirsk, 630090, Russia,Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, Pr. Lavrentieva 3, Novosibirsk, 630090, Russia,Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, Pr. Lavrentieva 3, Novosibirsk, 630090, Russia,Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;

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入库时间 2022-08-17 13:16:09

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Synthesis and characterization of a new Keggin anion: [BeW_(12)O_(40)]~(6-)

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