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1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid

机译:路易斯酸稳定的1,2,4,3-三氮杂硼烷基中性氧杂硼烷

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摘要

The first example of 1,2,4,3-triazaborole-based oxoborane has been synthesized via hydrogen migration upon the coordination of AlCl_3 to the corresponding borinic acid. X-ray diffraction analysis and computational study disclosed the partial B=O double-bond property.
机译:基于1,2,4,3-三氮杂硼烷的氧杂硼烷的第一个例子已经通过在AlCl 3配位到相应的硼酸上的氢迁移而合成。 X射线衍射分析和计算研究揭示了部分B = O双键性质。

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  • 来源
    《Chemical Communications》 |2014年第62期|8561-8564|共4页
  • 作者单位

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore;

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore;

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore;

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore;

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore;

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore;

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