A unique copper-catalyzed cross-coupling reaction by hydrogen (H_2) removal for the stereoselective synthesis of 3-phosphoindoles

An-Xi Zhou; Liu-Liang Mao; Gang-Wei Wang; Shang-Dong Yang

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A unique copper-catalyzed cross-coupling reaction by hydrogen (H_2) removal for the stereoselective synthesis of 3-phosphoindoles

机译：独特的铜催化的氢（H_2）去除交联反应，用于立体选择性合成3-磷酸吲哚

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摘要

The first Cu(Ⅰ)-catalyzed cross-coupling reaction by hydrogen (H_2) removal for the stereoselective synthesis of 3-phosphoindoles is reported. Going beyond the oxidative dehydrogenative coupling reactions reported recently, this reaction completely omits the oxidant and base, producing hydrogen (H_2) as the only byproduct.

机译：报道了第一个通过氢（H_2）去除Cu（Ⅰ）催化的交叉偶联反应，用于立体选择性合成3-磷酸吲哚。除了最近报道的氧化脱氢偶联反应之外，该反应完全省略了氧化剂和碱，产生了氢（H_2）作为唯一的副产物。

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来源
《Chemical Communications》 |2014年第62期|8529-8532|共4页
作者
An-Xi Zhou; Liu-Liang Mao; Gang-Wei Wang; Shang-Dong Yang;
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作者单位

State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China;

State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China;

State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China;

State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China,State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Lanzhou 730000, P. R. China;

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3. New methods in organic synthesis through copper-catalyzed borylation reactions: Stereoselective synthesis of 1,4-diols and vinylboronates [J] . Alfaro R., Parra A., Alemán J., Synlett . 2013,第7期

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4. Stereoselective Synthesis of Monofluoroalkenes Using Cross-Coupling Reactions [C] . Shoji Hara American Chemical Society Symposium on Fluorine-Containing Synthons . 2005

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5. Stereoselective synthesis of tetrasubstituted alkenes and copper-catalyzed interrupted cross-coupling reactions. [D] . You, Wei. 2016

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A unique copper-catalyzed cross-coupling reaction by hydrogen (H_2) removal for the stereoselective synthesis of 3-phosphoindoles

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