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Iron(Ⅲ)-salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles

机译:铁(Ⅲ)-salan配合物催化β-酮酸酯和N-Boc羟吲哚的高度对映选择性氟化和羟基化

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摘要

Chiral iron(Ⅲ)-salan complexes catalysed highly enantioselective α-fluorination and α-hydroxylation of β-keto esters and N-Boc oxindoles to give the corresponding products in high yields and good-to-excellent ee values under mild reaction conditions.
机译:手性铁(Ⅲ)-salan配合物在温和的反应条件下,催化β-酮基酯和N-Boc羟吲哚的高对映选择性α-氟化和α-羟基化,从而以高收率和良好的ee值得到相应的产物。

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  • 来源
    《Chemical Communications》 |2014年第58期|7870-7873|共4页
  • 作者单位

    Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China;

    Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China;

    Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China;

    Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China,Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China;

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