Aqueous aerobic oxidation of alkyl arenes and alcohols catalyzed by copper(Ⅱ) phthalocyanine supported on three-dimensional nitrogen-doped graphene at room temperature

摘要

Copper(Ⅱ) tetrasulfophthalocyanine supported on three-dimensional nitrogen-doped graphene-based frameworks was synthesized and introduced as a bifunctional catalyst for selective aerobic oxidation of alkyl arenes and alcohols to the corresponding carbonyl compounds. The ease of catalyst separation, high turnover, low catalyst loading and recyclability could potentially render it applicable in industrial setting.