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Synthesis and spectroscopic properties of chiral binaphthyl-linked subphthalocyanines

机译:手性联萘连接的亚酞菁的合成及光谱性质

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摘要

Chiral binaphthyl-linked subphthalocyanines (SubPcs) (1) have been prepared by the cyclotrimerization reaction of a phthalonitrile linked with (R)- and (S)-2,2'-binaphthyl in the presence of BCl_3, and characterized by various spectroscopies including NMR, electronic absorption, CD, and MCD, as well as electrochemistry.
机译:手性联萘连接的亚酞菁(SubPcs)(1)是通过在(BCl_3)存在下与(R)-和(S)-2,2'-联萘连接的邻苯二甲腈的环三聚反应制备的,其特征在于包括NMR,电子吸收,CD和MCD以及电化学。

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  • 来源
    《Chemical Communications》 |2014年第57期|7663-7665|共3页
  • 作者单位

    Department of Chemistry, Graduate School of Science, Tohoku University,Sendai 980-8578, Japan,Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing, 100083, China;

    Department of Chemistry, Graduate School of Science, Tohoku University,Sendai 980-8578, Japan;

    Department of Chemistry, Graduate School of Science, Tohoku University,Sendai 980-8578, Japan;

    Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing, 100083, China;

    Department of Chemistry, Graduate School of Science, Tohoku University,Sendai 980-8578, Japan;

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