Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity

Catatin Maxim; Sylvie Ferlay; Hiroko Tokoro; Shin-Ichi Ohkoshi; Cyrille Train

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Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity

机译：表现出高质子传导性的3D双金属草酸盐基长距离有序磁体的非典型化学计量

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摘要

The reproducible formation of a 3D oxalate based coordination compound of formula (NH_4)_5[Mn~Ⅱ_2Cr~Ⅲ_3(ox)_9]·10H_2O, with an unusual Mn~Ⅱ/Cr~Ⅲ ratio, is presented. The original topology of the anionic network leads to antiferromagnetic long-range ordering whereas its guests favour high humidity-dependent proton conductivity.

机译：提出了可重复形成的式（NH_4）_5 [Mn〜Ⅱ_2Cr〜Ⅲ_3（ox）_9]·10H_2O的3D草酸盐基配位化合物，其中Mn〜Ⅱ/ Cr〜Ⅲ比值异常。阴离子网络的原始拓扑结构导致反铁磁的远程有序排列，而其来宾则倾向于高湿度相关的质子传导性。

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《Chemical Communications》 |2014年第42期|5629-5632|共4页
作者
Catatin Maxim; Sylvie Ferlay; Hiroko Tokoro; Shin-Ichi Ohkoshi; Cyrille Train;
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作者单位

Molecular Tectonic Laboratory, UMR UDS-CNRS 7140, Universite de Strasbourg, Institut Le Bel, 4, rue Blaise Pascal, F-67000 Strasbourg, Prance,CNRS, LNCMI, 25 rue des Martyrs, B.P. 166, F-38042 Grenoble cedex 9, France,University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Laboratory, Str. Dumbrava Rosie nr. 23, 020464-Bucharest, Romania;

Molecular Tectonic Laboratory, UMR UDS-CNRS 7140, Universite de Strasbourg, Institut Le Bel, 4, rue Blaise Pascal, F-67000 Strasbourg, Prance,Institut Universitaire de France (IUF), 103 bld Saint-Michel, F-75005 Paris, France;

Department of Chemistry, School of Science, University of Tokyo, Tokyo 113-0033, Japan;

Department of Chemistry, School of Science, University of Tokyo, Tokyo 113-0033, Japan;

CNRS, LNCMI, 25 rue des Martyrs, B.P. 166, F-38042 Grenoble cedex 9, France,University Grenoble Alpes, LNCMI, F-38041 Grenoble Cedex 9, France,Institut Universitaire de France (IUF), 103 bld Saint-Michel, F-75005 Paris, France;

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入库时间 2022-08-17 13:15:49

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1. Magnetic Investigation of an Atypical Three-Dimensional Bimetallic Oxalate-Based Magnet [J] . Simonet Virginie, Damay Francoise, Ferlay Sylvie, The journal of physical chemistry, C. Nanomaterials and interfaces . 2020,第1期

机译：非典型三维双金属磁铁基磁铁的磁力研究
2. Spin crossover Fe-II complexes as templates for bimetallic oxalate-based 3D magnets [J] . Coronado E, Mascaros JRG, Gimenez-Lopez MC, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第9a11期

机译：自旋交叉Fe-II复合物作为基于双金属草酸酯的3D磁体的模板
3. Synthesis and Characterization of a Bimetallic Oxalate-Based Magnet: [(C4H9)4P][M(II)Cr(ox)3] M(II) = Mn, Fe, Co, Ni, Cu [J] . F. Martak, D. Onggo, Ismunandar, Current Research in Chemistry . 2009,第1期

机译：草酸双金属磁体的合成与表征：[（C4H9）4P] [M（II）Cr（ox）3] M（II）= Mn，Fe，Co，Ni，Cu
4. Octacyanoniobate(IV)-based molecular magnets revealing 3D long-range order [C] . R Pelka, D Pinkowicz, O Drath Joint European Magnetic Symposia . 2010

机译：octacyAnoniobate（iv）基于分子磁铁，揭示了3D远程顺序
5. The design and investigation of bimetallic ruthenium complexes exhibiting proton-coupled intramolecular electron transfer. [D] . Slattery, Spencer James. 1993

机译：展示质子偶联分子内电子转移的双金属钌配合物的设计和研究。
6. Atypical Stoichiometry for a 3D Bimetallic Oxalate- Based Long-range Ordered Magnet Exhibiting High Proton Conductivity [O] . Maxim, Catalin, Ferlay, Sylvie, Tokoro, Hiroko, 2014

机译：具有高质子电导率的基于3D双金属草酸盐的远程有序磁体的非典型化学计量

Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity

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