A chiral spin crossover metal-organic framework

Wei Liu; Xin Bao; Ling-Ling Mao; Jiri Tucek; Radek Zboril; Jun-Liang Liu; Fu-Sheng Guo; Zhao-Ping Ni; Ming-Liang Tong

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A chiral spin crossover metal-organic framework

机译：手性自旋交联金属有机骨架

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摘要

A chiral metal-organic framework exhibiting spin crossover (SCO) property, [Fe~(Ⅱ)(mptpy)_2]·EtOH·0.2DMF (1·solv), has been solvo-thermally synthesized through spontaneous resolution. It displays remarkable stability and two-step SCO at (T_(c1) = 200 K) and above (T_(c2) = 357 K) room temperature.

机译：通过自发拆分溶剂热合成了具有自旋交联（SCO）性质的手性金属有机骨架[Fe〜（Ⅱ）（mptpy）_2]·EtOH·0.2DMF（1·solv）。在室温（T_（c1）= 200 K）和高于室温（T_（c2）= 357 K）时，它具有出色的稳定性和两步SCO。

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来源
《Chemical Communications》 |2014年第31期|4059-4061|共3页
作者
Wei Liu; Xin Bao; Ling-Ling Mao; Jiri Tucek; Radek Zboril; Jun-Liang Liu; Fu-Sheng Guo; Zhao-Ping Ni; Ming-Liang Tong;
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作者单位

School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China;

Department of Chemistry, School of Chemical Engineering, Nanjing University of Science and Technology, 210094 Nanjing, P. R. China;

School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China;

Regional Centre of Advanced Technologies and Materials, Department of Experimental Physics, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic;

Regional Centre of Advanced Technologies and Materials, Department of Experimental Physics, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic;

School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China;

School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China;

School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China;

School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China;

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入库时间 2022-08-17 13:15:26

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2. Cooperative Large-Hysteresis Spin-Crossover Transition in the Iron(II) Triazolate [Fe(ta)(2)] Metal-Organic Framework [J] . Grzywa Maciej, Roess-Ohlenroth Richard, Muschielok Christoph, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第15期

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3. Host Polytypism and Structural Modulation in Two-Dimensional Fe(NCS)(2)-Based Metal-Organic Frameworks: Can Spin-Crossover Transitions Be Predicted? [J] . De La Pinta Noelia, Klar Paul Benjamin, Breczewski Tomasz, Crystal growth & design . 2020,第1期

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4. A Three-Dimensional Metal-Organic Framework Displaying Guest-Dependent Spin-Crossover Behaviour [C] . Feng Shao, Jia-Jia Zhuang, Gang Luo International Conference on Smart Materials Technologies . 2018

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5. Chiral and Stereoelectronically Controlled Modules in Complex Metal-Organic Frameworks [D] . Li, Qiaowei 2010

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6. Dual-Mode Induction of Tunable Circularly Polarized Luminescence from Chiral Metal-Organic Frameworks [O] . Tonghan Zhao, Jianlei Han, Xue Jin, 2020

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7. Enhanced Cooperativity in Supported Spin-Crossover Metal-Organic Frameworks [O] . Groizard, Thomas, Papior, Nick, Le Guennic, Boris, 2017

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A chiral spin crossover metal-organic framework

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