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An unprecedented octanuclear copper core with C_(3i) symmetry and a paramagnetic ground statef

机译:具有C_(3i)对称性和顺磁性基态的前所未有的八核铜芯f

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摘要

A complex of copper, possessing an octanuclear structure of high symmetry, has been prepared by a spontaneous self-assembly reaction of Cu(BF_4)_2 with N-tert-butyldiethanolamine and reveals a paramagnetic ground state.
机译:Cu(BF_4)_2与N-叔丁基二乙醇胺的自发自组装反应制备了具有高对称八角形结构的铜配合物,并显示出顺磁性基态。

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  • 来源
    《Chemical Communications》 |2014年第26期|3431-3434|共4页
  • 作者单位

    Centra de Quimica Estrutural, Complexo Ⅰ, Instituto Superior Tecnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal;

    Faculty of Chemistry, University of Wroclaw, 14 Joliot-Curie Str., 50-383, Wroclaw, Poland;

    Centra de Quimica Estrutural, Complexo Ⅰ, Instituto Superior Tecnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal;

    Centra de Quimica Estrutural, Complexo Ⅰ, Instituto Superior Tecnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal;

    National High Magnetic Field Laboratory, Florida State University, 1800 E. Paul Dirac Drive, Tallahassee, Florida 32310, USA;

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  • 入库时间 2022-08-17 13:15:12

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