Copper-catalyzed ortho-C-H amination of protected anilines with secondary amines

Angel Manu Martinez; Nuria Rodriguez; Ramon Gomez Arrayas; Juan C. Carretero

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Copper-catalyzed ortho-C-H amination of protected anilines with secondary amines

机译：受保护的苯胺与仲胺的铜催化邻-C-H胺化

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摘要

A practical Cu-catatyzed picolinamide-directed o-amination of anilines showing excellent mono-substitution selectivity and high functional group tolerance has been developed.

机译：已经开发出一种实用的铜催化苯胺的吡咯啉酰胺定向的O-胺化反应，显示出优异的单取代选择性和高官能团耐受性。

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《Chemical Communications》 |2014年第21期|2801-2803|共3页
作者
Angel Manu Martinez; Nuria Rodriguez; Ramon Gomez Arrayas; Juan C. Carretero;
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Departamento de Quimica Organica, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid, Spain;

Departamento de Quimica Organica, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid, Spain;

Departamento de Quimica Organica, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid, Spain;

Departamento de Quimica Organica, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid, Spain;

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1. Copper-Catalyzed Oxalamide-Directed ortho-C-H Amination of Anilines with Alkylamines [J] . Wu Peng, Huang Wei, Cheng Tai-Jin, Organic letters . 2020,第13期

机译：用烷基胺掺铜催化的氧化盐酰胺 - 苯胺的苯胺胺化
2. Copper-Catalyzed Electrochemical C-H Amination of Arenes with Secondary Amines [J] . Yang Qi-Liang, Wang Xiang-Yang, Lu Jia-Yan, Journal of the American Chemical Society . 2018,第36期

机译：仲胺对芳烃的铜催化电化学C-H胺化
3. Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles [J] . Cheng Zhang, Ya-Hui Wang, Xin-Hu Hu Advanced synthesis & catalysis . 2012,第14a15期

机译：手性三齿P，N，N配体，用于高对映选择性铜催化的丙炔化胺，伯胺和仲胺均为亲核剂
4. Reductive Cross-amination between Aniline or Nitroarene Derivatives and Alkylamines Catalyzed by Polysilane-immobilized Metal Nanoparticles [C] . Aya SUZUKI, Hiroyuki MIYAMURA, Shu KOBAYASHI 日本化学会春季年会講演予稿集 . 2018

机译：通过聚硅烷固定金属纳米颗粒催化的苯胺或硝基芳衍生物和烷基胺之间的还原交叉胺化
5. Part A. Diastereoselective synthesis of protected secondary amines via reduction /alkylation or deprotonation /alkylation of N-diphenylphosphinylimines. Part B. Synthesis of secondary amines via 1,2-addition of organometallic reagents to N-diphenylphosphinylimines and subsequent alkylation [D] . Shin, Hyunshun 2001

机译：A部分：通过N-二苯基膦亚胺的还原/烷基化或去质子化/烷基化的非对映选择性合成保护的仲胺。 B部分：通过将有机金属试剂1,2-加成到N-二苯基膦亚胺和随后的烷基化反应来合成仲胺
6. Copper-catalyzed dehydrogenative γ-C(sp3)-H amination of saturated ketones for synthesis of polysubstituted anilines [O] . Rong Hu, Fa-Jie Chen, Xiaofeng Zhang, -1

机译：铜催化饱和酮的脱氢γ-C（sp3）-H胺化反应合成多取代苯胺
7. Copper-catalyzed ortho-C-H amination of protected anilines with secondary amines [O] . Martínez, Ángel Manu, Rodríguez, Nuria, Arrayás, Ramón Gómez, 2014

机译：铜催化的受保护的苯胺与仲胺的邻C-H胺化反应

Copper-catalyzed ortho-C-H amination of protected anilines with secondary amines

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