First lanthanide dipolar complexes for second-order nonlinear optics

Senechal K; Toupet L; Ledoux I; Zyss J; Le Bozec H; Maury O

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First lanthanide dipolar complexes for second-order nonlinear optics

机译：二阶非线性光学的第一镧系元素偶极复合物

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摘要

New push-pull NLO-phores based on lanthanide complexes (Ln = La, Gd, Dy, Yb) featuring an annelated dibutylaminophenyl functionalised terpyridyl ligand have been synthesised and shown to exhibit large first-order hyperpolarizability.

机译：合成了基于镧系元素配合物（Ln = La，Gd，Dy，Yb）的新型推挽式NLO-phors，其特征是具有经退火的二丁基氨基苯基官能化的吡啶基配体，并显示出较大的一阶超极化性。

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来源
《Chemical Communications》 |2004年第19期|p. 2180-2181|共2页
作者
Senechal K; Toupet L; Ledoux I; Zyss J; Le Bozec H; Maury O;
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作者单位

Univ Rennes 1, CNRS, UMR 6509, Inst Chim Rennes, F-35042 Rennes, France;

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原文格式 PDF
正文语种 eng
中图分类化学;
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CHROMOPHORES; DERIVATIVES;

机译：铬染料;衍生物;
入库时间 2022-08-17 13:33:15

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2. Fluorinated β-Diketonate Diglyme Lanthanide Complexes as New Second-Order Nonlinear Optical Chromophores: The Role of f Electrons in the Dipolar and Octupolar Contribution to Quadratic Hyperpolarizability [J] . Adriana Valore Elena Cariati Stefania Righetto Dominique Roberto Francesca Tessore Renato Ugo Ignazio L. Fragal Maria Elena Fragal Graziella Malandrino Filippo De Angelis Leonardo Belpassi Isabelle Ledoux-Rak Khuyen Hoang Thi and Joseph Zyss Journal of the American Chemical Society . 2010,第13期

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3. Organometallic Complexes for Nonlinear Optics. 43. Quadratic Optical Nonlinearities of Dipolar Alkynylruthenium Complexes with Phenyleneethynylene/Phenylenevinylene Bridges [J] . Luca Rigamonti, Bandar Babgi, Marie P. Cifuentes, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第8期

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4. Second-order Nonlinear Optical Properties Of Bond Alternating Dipolar Structures [C] . Cai, Y.M., Yamada, . 2001

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7. Nonlinear optical activity in dipolar organic-lanthanide complexes [O] . Law GL, Wong KL, Lau KK, 2010

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8. Dipolar Relaxation in a Second-Order Nonlinear Optical Interpenetrating PolymerNetwork [R] . Chen, J. I., Marturunkakul, S., Li, L., 1993

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First lanthanide dipolar complexes for second-order nonlinear optics

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