Engineering silver(Ⅰ) coordination networks through hydrogen bonding

摘要

The silver(Ⅰ) coordination networks [Ag_2(μ-O_2CCF_3)_2(μ-NN)_2]_∞ exist as a polymer of macrocycles or a double-stranded polymer when NN = 1,2-C_6H_4{NHC(O)-4-C_5H_4N}_2 or 1,2-C_6H_4{NHC(O)-3-C_5H_4N}_2, respectively. Crystal engineering of the polymers is achieved through interchain hydrogen bonds.