Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution

Chiang Y; Kresge AJ; Onyido I; Richard JP; Wan P; Xu MS

首页> 外文期刊>Chemical Communications >Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution

【24h】

Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution

机译：水溶液中对苯甲酰基苯乙酸的快速光解脱羧反应产生的强酸性细长烯醇酮化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Photodecarboxylation of p-benzoylphenylacetic acid in aqueous solution produces the elongated enol 5, whose strength as an oxygen acid (pQE(a)(E) 7.67) makes it more acidic than simple enol analogs by several orders of magnitude.

机译：对苯甲酰基苯基乙酸在水溶液中的光脱羧产生了细长的烯醇5，其强度为含氧酸（pQE（a）（E）7.67），比简单的烯醇类似物酸性高几个数量级。

著录项

来源
《Chemical Communications》 |2005年第33期|p. 4231-4233|共3页
作者
Chiang Y; Kresge AJ; Onyido I; Richard JP; Wan P; Xu MS;
展开▼
作者单位

Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
入库时间 2022-08-17 13:31:49

相似文献

外文文献
中文文献
专利

1. Ketonization of the unusually acidic elongated enol generated by flash photolytic decarboxylation of p-formylphenylacetic acid in aqueous solution [J] . Yvonne Chiang, Kirill Kolmakov, A.Jerry Kresge Canadian Journal of Chemistry . 2008,第2期

机译：水溶液中对甲酰基苯乙酸的快速光解脱羧反应生成的非常规酸性细长烯醇的酮化
2. Ketonization of the unusually acidic elongated enol generated by flash photolytic decarboxylation of p-formylphenylacetic acid in aqueous solution [J] . Chiang Yvonne, Kolmakov Kirill, Kresge A J. Canadian Journal of Chemistry . 2008,第2期

机译：水溶液中对甲酰基苯基乙酸的快速光解脱羧反应生成的非常规酸性细长烯醇的酮化
3. The 2-oxo-3,3,5,5-tetramethylcyclopentanecarboxylic acid keto-enol system in aqueous solution-Generation of the enol by flash photolytic Wolff rearrangement of 2-diazo-4,4,6,6-tetramethylcyclohexane-l,3-dione followed by hydration of the acylketene t [J] . Y. Chiang, A.J. Kresge, V.A. Nikolaev Canadian Journal of Chemistry . 2005,第1期

机译：水溶液中的2-oxo-3,3,3,5,5-四甲基环戊烷羧酸酮-烯醇体系-2-重氮-4,4,6,6-四甲基环己烷-1,3的快速光解Wolff重排生成烯醇-二酮，然后水合酰基烯酮
4. Water Assisted and Acid Catalyzed Decarboxylation Reactions of Ketoprofen in Aqueous Solutions [C] . David Lee Phillips, Ming-De Li, Yong Du, International Conference on Raman Spectroscopy . 2010

机译：水辅助和酸催化酮丁香丁酸脱羧反应水溶液
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. Modeling solubility and acid–base properties of some amino acids in aqueous NaCl and (CH3)4NCl aqueous solutions at different ionic strengths and temperatures [O] . Clemente Bretti, Ottavia Giuffrè, Gabriele Lando, -1

机译：在不同离子强度和温度下模拟某些氨基酸在NaCl和（CH3）4NCl水溶液中的溶解度和酸碱性质
7. Flash photolytic generation and study of ketenes: acid- catalysed hydration in aqueous solution+ [O] . J. Andraos, A. J. Kresge 1991

机译：闪光光解产生和乙烯酮的研究：在水溶液中酸催化水合+
8. THE PREPARATION OF m- AND p- HYDROXY-BENZOIC ACIDS (C14 CARBOXYL) BY RADIOLYSIS OF AN AQUEOUS SOLUTION OF BENZOIC ACID (C14 CARBOXYL) [R] . A. DAVISON 1968

机译：苯甲酸（C14羧基）水溶液的辐解制备间 - 和对 - 羟基苯甲酸（C14羧基）

Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution

摘要

著录项

相似文献

相关主题

期刊订阅