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Selective sensing of Cu(Ⅱ) at ng ml~(-1) level based on phosphorescence quenching of 1-bromo-2-methylnaphthalene sandwiched in sodium deoxycholate dimer

机译:基于夹在脱氧胆酸钠二聚体中的1-溴-2-甲基萘的磷光猝灭,选择性检测ng ml〜(-1)浓度的Cu(Ⅱ)

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摘要

Using sodium deoxycholate as a protective medium, the selective recognition of Cu(Ⅱ) at ng ml~(-1) level is realized through dynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene (BMN) without deoxygenation. The limit of detection is 4.32 ng ml~(-1), and the relative standard deviation is 1% at 10 μM, linear up to 1 x 10~(-5) M.
机译:以脱氧胆酸钠为保护介质,通过对1-溴-2-甲基萘(BMN)进行动态磷光猝灭而无需脱氧,从而选择性地识别出ng ml〜(-1)水平的Cu(Ⅱ)。检测限为4.32 ng ml〜(-1),相对标准偏差在10μM时为1%,线性最高1 x 10〜(-5)M.

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