Stereochemistry of the reaction catalysed by 2-hydroxy-6-keto-6-phenyl-hexa-2,4-dienoic acid 5,6-hydrolase (BphD)

Li JJ; Bugg TDH

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Stereochemistry of the reaction catalysed by 2-hydroxy-6-keto-6-phenyl-hexa-2,4-dienoic acid 5,6-hydrolase (BphD)

机译：2-羟基-6-酮基-6-苯基-己基-2,4-二烯酸5,6-水解酶（BphD）催化的反应的立体化学

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摘要

The stereochemical course of the reaction catalysed by C-C hydrolase BphD from Burkholderia xenovorans LB400 occurs with replacement of a benzoyl group by hydrogen with overall retention of stereochemistry.

机译：异种伯克霍尔德菌LB400的C-C水解酶BphD催化的反应的立体化学过程是通过氢取代苯甲酰基而完全保留了立体化学而发生的。

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来源
《Chemical Communications》 |2005年第1期|p. 130-132|共3页
作者
Li JJ; Bugg TDH;
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作者单位

Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
HYDROLASE BPHD; ENZYMES; DEGRADATION; INTERMEDIATE; PURIFICATION; MECHANISM; CLEAVAGE;

机译：水解酶;酶;降解;中间体;纯化;机理;解理;
入库时间 2022-08-17 13:31:12

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机译：Rhodococcus sp。的微生物2-Hydroxy1-6-oxo-6-phenylhexa-2，4-dennoic acid（HPDA）水解酶（BphD酶）的三维结构。 PCB降解途径中的RHA1菌株
2. Synthetic 6-aryl-2-hydroxy-6-ketohexa-2,4-dienoic acid substrates for C-C hydrolase BphD: investigation of a general base catalytic mechanism [J] . Speare DM, Fleming SM, Beckett MN, Organic & biomolecular chemistry . 2004,第20期

机译：C-C水解酶BphD的合成6-芳基-2-羟基-6-酮六-2,4-二烯酸底物：通用碱催化机理的研究
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4. A comparison of the reaction mechanism in acid- and in basic-catalysed gas-phase methylation of phenol [C] . N. Ballarini, F. Cavani, S. Guidetti International Federation of European Zeolite Associations Conference . 2008

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5. Structural studies of BphD LBb400 variants: Insights into the reaction mechanism of MCP hydrolases [D] . Ghosh, Subhangi 2011

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6. Recombinant 10-formyltetrahydrofolate dehydrogenase catalyses both dehydrogenase and hydrolase reactions utilizing the synthetic substrate 10-formyl-58-dideazafolate. [O] . S A Krupenko, C Wagner, R J Cook 1995

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7. Three-dimensional Structure of Microbial 2-Hydroxyl-6-oxo-6-phenylhexa-2,4-dienoic Acid (HPDA) Hydrolase (BphD Enzyme) from Rhodococcus sp. Strain RHA1, in the PCB Degradation Pathway. [O] . Narayanasamy NANDHAGOPAL, Toshiya SENDA, Takashi HATTA, 1997

机译：微生物2-羟基-6-氧代 - 6-苯基釜-2,4-二烯酸乙酯（HPDA）水解酶（BPHD酶）的三维结构来自rhodoccccus sp。菌株RHA1，在PCB降解途径中。

Stereochemistry of the reaction catalysed by 2-hydroxy-6-keto-6-phenyl-hexa-2,4-dienoic acid 5,6-hydrolase (BphD)

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