Novel π-complexes of divalent silicon: mixed substituted neutral sandwich compounds and the half-sandwich cation (~iPr_5C_5)Si~+

Peter Jutzi; Andreas Mix; Beate Neumann; Britta Rummel; Hans-Georg Stammler

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Novel π-complexes of divalent silicon: mixed substituted neutral sandwich compounds and the half-sandwich cation (~iPr_5C_5)Si~+

机译：二价硅的新型π复合物：混合取代的中性夹心化合物和半夹心阳离子（〜iPr_5C_5）Si〜+

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The pentamethylcyclopentadienylsilicon(II) cation, Me_5C_5Si~+ opens up access to novel silicocene derivatives; the penta-iso- propylcyclopentadienylsilicon(II) cation, ~iPr_5C_5Si~+, is obtained by reaction of the mixed silicocene (~iPr_5C_5)(Me_5C_5)Si with H(OEt_2)_2~+Al[OC(CF_3)_3]_4~-.

机译：五甲基环戊二烯基硅（II）阳离子Me_5C_5Si〜+使得人们可以接触到新型的全新世衍生物；五异丙基环戊二烯基硅（II）阳离子〜iPr_5C_5Si〜+是通过混合新世代（〜iPr_5C_5）（Me_5C_5）Si与H（OEt_2）_2〜+ Al [OC（CF_3）_3] _4〜 -

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来源
《Chemical Communications》 |2006年第33期|p.3519-3521|共3页
作者
Peter Jutzi; Andreas Mix; Beate Neumann; Britta Rummel; Hans-Georg Stammler;
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Department of Chemistry, University of Bielefeld, Universitaetsstrasse 25, D-33615 Bielefeld, Germany;

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正文语种 eng
中图分类化学;
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入库时间 2022-08-17 13:29:59

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Novel π-complexes of divalent silicon: mixed substituted neutral sandwich compounds and the half-sandwich cation (~iPr_5C_5)Si~+

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