Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes

Douglas TM; Le Notre H; Brayshaw SK; Frost CG; Weller AS

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Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes

机译：膦-烯烃配体：催化活性铑配合物的简便脱氢途径

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摘要

Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine - olefin complexes, some of which are catalytically active for 1,4-additions.

机译：三环戊基膦的简单，金属介导的（无受体）脱氢直接提供了铑螯合膦-烯烃复合物，其中一些对1,4-加成具有催化活性。

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来源
《Chemical Communications》 |2006年第32期|p. 3408-3410|共3页
作者
Douglas TM; Le Notre H; Brayshaw SK; Frost CG; Weller AS;
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作者单位

Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; CATALYZED ASYMMETRIC 1; 4-ADDITION; CONJUGATE ADDITION; ARYLZINC REAGENTS; ARYLBORONIC ACIDS; SUCCINIC ESTERS; CHLOROTRIMETHYLSILANE; ACTIVATION; REACTIVITY; ALDEHYDES;

机译：阿尔法;非饱和不饱和羰基化合物;催化不对称1;4-添加;共轭加成;芳烃添加剂;芳烃酸;蔗糖酯;氯代三甲基硅烷;活化;反应活性;醛;
入库时间 2022-08-17 13:29:57

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Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes

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