Anionic ring-opening polymerization of a strained phosphirene: A route to polyvinylenephosphines

Vanderark LA; Clark TJ; Rivard E; Manners I; Slootweg JC; Lammertsma K

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Anionic ring-opening polymerization of a strained phosphirene: A route to polyvinylenephosphines

机译：磷腈的阴离子开环聚合：通往聚乙烯基膦的途径

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摘要

A strained 1-phenyl-2,3-dimethylphosphirene undergoes anionic ring-opening polymerization upon initiation with n-butyl lithium at ambient temperature to yield polyvinylenephosphine, an unsaturated organophosphorus polymer.

机译：应变的1-苯基-2,3-二甲基磷腈在环境温度下用正丁基锂引发时会发生阴离子开环聚合反应，从而生成不饱和有机磷聚合物聚乙烯亚膦。

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来源
《Chemical Communications》 |2006年第31期|p. 3332-3333|共2页
作者
Vanderark LA; Clark TJ; Rivard E; Manners I; Slootweg JC; Lammertsma K;
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作者单位

Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England;

Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada;

Vrije Univ Amsterdam, Fac Sci, Dept Chem, NL-1081 HV Amsterdam, Netherlands;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
CONJUGATED POLYMERS; BONDS; CHEMISTRY; THIONYLPHOSPHAZENE; MACROMOLECULES; COPOLYMERS; REACTIVITY; COMPLEXES; CATALYSIS; BLOCK;

机译：共轭聚合物;键;化学性质;亚硫酰膦;大分子;共聚物;反应性;络合物;催化;嵌段;

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2. Anionic Ring-Opening Polymerization of Methyl 4,6-O-Benzylidene-2,3-O-carbonyl-alpha-D-glucopyranoside:A First Example of Anionic Ring-Opening Polymerization of Five-Membered Cyclic Carbonate without Elimination of CO_2 [J] . Osamu Haba, Haruka Tomizuka, Takeshi Endo Macromolecules . 2005,第9期

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3. Ring-Opening Polymerization of a Strained [3]Nickelocenophane: A Route to Polynickelocenes, a Class of S = 1 Metallopolymers [J] . Sladjana Baljak, Andrew D. Russell, Samantha C. Binding, Journal of the American Chemical Society . 2014,第16期

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4. Development of High-speed Reactive Processing System for Carbon Fiber-reinforced Polyamide-6 Composite : In-situ Anionic Ring-opening Polymerization [C] . Sang-Woo Kim, Dong Gi Seong, Jin-Woo Yi, International Conference on Times of Polymers TOP and Composites . 2016

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5. Combination of anionic, ring-opening metathesis, living radical polymerization for novel nanostructured polymer synthesis. [D] . Cheng, Chong. 2003

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6. Polymers and Related Composites via Anionic Ring-Opening Polymerization of Lactams: Recent Developments and Future Trends [O] . Tatyana Ageyeva, Ilya Sibikin, József Karger-Kocsis 2018

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8. Ring-Opening Polymerization of Strained Cyclotetrasilanes as a New Route Towards Well Defined Polysilylenes. [R] . Cypryk, M., Chrusciel, J., Fossum, E., 1994

机译：应变环四硅烷的开环聚合作为定义明确的聚硅烯的新途径。

Anionic ring-opening polymerization of a strained phosphirene: A route to polyvinylenephosphines

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