Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds

Kobayashi K; Ueno M; Kondo Y

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Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds

机译：磷腈催化的乙酸三甲基甲硅烷基酯与羰基化合物的缩合

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摘要

The t-Bu-P4 base was found to be an excellent catalyst for the condensation of trimethylsilylacetate or trimethylacetonitrile with carbonyl compounds to form functionalized alkenes and beta-enaminoesters were also synthesized by the condensation with formanilides.

机译：发现t-Bu-P4碱是乙酸三甲基甲硅烷基酯或三甲基乙腈与羰基化合物缩合以形成官能化烯烃的极佳催化剂，并且通过与甲腈缩合也可合成β-烯胺酯。

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来源
《Chemical Communications》 |2006年第29期|p. 3128-3130|共3页
作者
Kobayashi K; Ueno M; Kondo Y;
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作者单位

Tohoku Univ, Grad Sch Pharmaceut Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
PETERSON OLEFINATION; T-BU-P4 BASE; POLYAMINOPHOSPHAZENES; FUNCTIONALIZATION; POLYMERIZATION;

机译：彼得森加烯烃;T-BU-P4碱;聚丙烯酰胺;功能化;聚合;
入库时间 2022-08-17 13:29:56

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Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds

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