Balancing framework densification with charged,halogen-bonded-π-conjugated linkages:[PPh_4]_2{[E-TTF-I2][Re_6Se_8(CN)_6]} versus [PPh_4]_2[EDT-TTF-I]_2{[EDT-TTF-I][Re_6Se_8(CN)_6]}

摘要

The ionic character of a set of two redox linkages and strong,directional halogen bonding at the organic-inorganic interface compromise to produce two materials sharing a common two-dimensional net,eventually extended in a third dimension,although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.