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首页> 外文期刊>Catalysis surveys from Asia >Dimeric & Polymeric Chiral Schiff Base Complexes and Supported BINOL Complexes as Potential Recyclable Catalysts in Asymmetric Kinetic Resolution and C-C Bond Formation Reactions
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Dimeric & Polymeric Chiral Schiff Base Complexes and Supported BINOL Complexes as Potential Recyclable Catalysts in Asymmetric Kinetic Resolution and C-C Bond Formation Reactions

机译：二聚和聚合手性席夫碱配合物和负载的BINOL配合物在不对称动力学拆分和C-C键形成反应中作为潜在的可回收催化剂

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摘要

This review is based on dimeric and polymeric chiral Schiff base metal complexes and chiral BINOL supported metal complexes as potential recyclable catalysts for kinetic resolution of racemic and meso epoxide and asymmetric C-C bond formation reactions e.g., asymmetric addition of diethylzinc to aldehydes, enantioselective addition of phenylacetylene to aldehydes, asymmetric nitro-Aldol reactions and asymmetric cyanation reaction.
机译：这项审查是基于二聚和聚合的手性席夫碱金属配合物和手性BINOL负载的金属配合物作为外消旋和内消旋环氧化物的动力学拆分和不对称CC键形成反应的潜在可回收催化剂，例如，将二乙基锌不对称添加到醛中，对映选择性地添加苯乙炔醛，不对称的硝基-Aldol反应和不对称的氰化反应。

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  • 来源
    《Catalysis surveys from Asia》 |2009年第2期|104-131|共28页
  • 作者

    S. H. R. Abdi; R. I. Kureshy; N. H. Khan; V. J. Mayani; H. C. Bajaj;

  • 作者单位

    Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G. B. Marg, Bhavnagar 364002, Gujarat, India;

    Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G. B. Marg, Bhavnagar 364002, Gujarat, India;

    Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G. B. Marg, Bhavnagar 364002, Gujarat, India;

    Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G. B. Marg, Bhavnagar 364002, Gujarat, India;

    Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G. B. Marg, Bhavnagar 364002, Gujarat, India;

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  • 关键词

    dimeric and polymeric chiral schiff bases; BINOL; asymmetric catalysis; kinetic resolution; racemic and meso epoxides; asymmetric C-C bond formation; nitro-aldol reaction; cyanation reaction;

    机译：二聚和聚合手性席夫碱;BINOL;不对称催化动力学分辨率外消旋和内消旋环氧化合物;不对称的C-C键形成;硝基-羟醛反应;氰化反应;

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