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Perovskite-type Oxide LaMnO3: An Efficient and Recyclable Heterogeneous Catalyst for the Wet Aerobic Oxidation of Lignin to Aromatic Aldehydes

机译:钙钛矿型氧化物LaMnO3 :一种高效可循环利用的木质素湿式好氧氧化成芳香醛的多相催化剂

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摘要

The perovskite-type oxide catalyst LaMnO3 prepared by the sol–gel method was found to be an efficient heterogeneous and recyclable catalyst for the wet aerobic oxidation of lignin to aromatic aldehydes. The lignin conversion rate and the yield of each aromatic aldehyde were enhanced significantly by the catalytic process as compared with the non-catalyzed process. Moreover, the activity, specific surface area and perovskite-type structure of the LaMnO3 catalyst remained nearly unchanged after five successive recycles of catalytic reactions.
机译:溶胶-凝胶法制备的钙钛矿型氧化物催化剂LaMnO3是木质素湿法好氧氧化为芳族醛的有效多相且可循环利用的催化剂。与非催化方法相比,通过催化方法,木质素转化率和每种芳族醛的产率显着提高。此外,LaMnO3 催化剂经过五次连续的循环反应后,其活性,比表面积和钙钛矿型结构几乎保持不变。

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  • 来源
    《Catalysis Letters》 |2008年第2期|106-111|共6页
  • 作者单位

    State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou 510640 Guangdong Province China;

    State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou 510640 Guangdong Province China;

    State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou 510640 Guangdong Province China;

    State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou 510640 Guangdong Province China;

    State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou 510640 Guangdong Province China;

    College of Medicine and Life Science Nanjing University of Technology Nanjing Jiangsu Province 210009 China;

    College of Medicine and Life Science Nanjing University of Technology Nanjing Jiangsu Province 210009 China;

    Department of Paper and Bioprocess Engineering State University of New York College of Environmental Science and Forestry 1 Forestry Drive Syracuse NY 13210 USA;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Perovskite-type oxide LaMnO3; Catalytic wet aerobic oxidation; Lignin; Aromatic aldehydes; Activity; Reusability;

    机译:钙钛矿型氧化物LaMnO3催化湿式好氧氧化木质素芳香醛活性重用;

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