Microbial Waste Biomass for Removal of Chromium(Ⅵ) from Chrome Effluent

摘要

Microbial waste biomass, a by-product of the fermentation industry, was developed as a biosorbent to remove hexavalent chromium (Cr) from the acidic effluent of a metal processing industry. In batch sorption, 100% Cr(Ⅵ) removal was achieved from aqueous solution in 30 min contact at pH 4.0-5.0. The Cr(Ⅵ) sorption equilibrium was evaluated using the Langmuir and Freundlich models, indicating the involvement of ion exchange and physicochemical interaction. Fourier transform infrared (FTIR) analysis revealed the presence of amine, hydroxyl, and imine functional groups present on the surface of microbial biomass that are involved in Cr binding. In a continuous sorption system, 95 mg L~(-1) of Cr(Ⅵ) was adsorbed before the column reached a breakthrough point of 0.1 mg L~(-1) Cr(Ⅵ) at the column outlet. An overall biosorption capacity of 12.6 mg Cr(Ⅵ) g~(-1) of dry microbial waste was achieved, including the partially saturated portion of the dynamic sorption zone. Insignificant change in metal removal was observed up to 10 cycles. In pilot-scale studies, 100% removal of Cr(Ⅵ) was observed up to 5 weeks, and the method was found to be cost-effective, commercially viable, and environmentally friendly, as it does not generate toxic chrome sludge.