Establishment of a database of emission factors for atmospheric pollutants from Chinese coal-fired power plants

摘要

Field measurements and data investigations were conducted for developing an emission factor database for inventories of atmospheric pollutants from Chinese coal-fired power plants. Gaseous pollutants and paniculate matter (PM) of different size fractions were measured using a gas analyzer and an electric low-pressure impactor (ELPI), respectively, for ten units in eight coal-fired power plants across the country. Combining results of field tests and literature surveys, emission factors with 95% confidence intervals (Cis) were calculated by boiler type, fuel quality, and emission control devices using bootstrap and Monte Carlo simulations. The emission factor of uncontrolled SO_2 from pulverized combustion (PC) boilers burning bituminous or anthracite coal was estimated to be 18.0S kg t~(-1) (i.e., 18.0 × the percentage sulfur content of coal, S) with a 95% Cl of 17.2S-18.5S. NQx emission factors for pulverized-coal boilers ranged from 4.0 to 11.2 kg t~(-1), with uncertainties of 14-45% for different unit types. The emission factors of uncontrolled PM_(2.5), PM_(10), and total PM emitted by PC boilers were estimated to be 0.4A (where A is the percentage ash content of coal), 1.5A and 6.9A kg t~(-1), respectively, with 95% Cis of 0.3A-0.5A, 1.1 A-1.9A and 5.8A-7.9A. The analogous PM values for emissions with electrostatic precipitator (ESP) controls were 0.032A (95% CI: 0.021A-0.046A), 0.065A (0.039A-0.092A) and 0.094A (0.0656A-0.132A) kg t~(-1), and 0.0147A (0.0092-0.0225A), 0.0210A (0.0129A-0.0317A), and 0.0231A (0.0142A-0.0348A) for those with both ESP and wet flue-gas desulfurization (wet-FGD). SO_2 and Nox emission factors for Chinese power plants were smaller than those of U.S. EPA AP-42 database, due mainly to lower heating values of coals in China. PM emission factors for units with ESP, however, were generally larger than AP-42 values, because of poorer removal efficiencies of Chinese dust collectors. For units with advanced emission control technologies, more field measurements are needed to reduce emission factor uncertainties.