Characteristics of total and methyl mercury in wet deposition in a coastal city, Xiamen, China: Concentrations, fluxes and influencing factors on Hg distribution in precipitation

摘要

Daily precipitation samples were collected from June 2012 to May 2013 at four observation sites in Xiamen, a coastal city of Southeast China. Concentrations of Total mercury (THg) and methyl mercury (MeHg) in precipitation were rigorously treated and determined. The annual volume-weighted mean concentrations of THg and MeHg at four sites were 12.3 and 0.053 ng L~(-1), and wet deposition fluxes of THg and MeHg were 14.04 μg m~(-2) yr~(-1) and 58.2 ng m~(-2) yr~(-1), respectively. MeHg could account for 0.43% of THg, and dissolved Hg contributed 55.4% to THg. There was no significant difference in THg concentration between monsoon and non-monsoon seasons, which was consistent with neither the general seasonal pattern of inland cities of China nor the report from the Gulf coast. Higher wet deposition flux of THg in monsoon season was a function of intense rainfall, whereas higher MeHg flux in non-monsoon season could attribute to increased MeHg concentration. Atmospheric Hg was more efficiently scavenged during the earlier period of the rain event. Positive correlations between precipitation depth and wet deposition fluxes suggested that rainfall played an important role in scavenging atmospheric Hg rather than diluting concentrations. Pearson correlation analysis combined with ions ratios implied that sea salt aerosols had an important impact on rainwater, but coal combustion and traffic emission could be the dominant factors influencing THg in precipitation.