Modeling of self-healing effects in polymeric composites

摘要

Polymers and polymer composites are used in many engineering applications, but they can loose a high rate of stiffness and strength due to internal micro cracks/damages during their lifetime cycle. These damages are very hard to detect and nearly impossible to repair. To avoid failure due to such damages, a self-healing system is considered where microencapsulated healing agents and catalysts are embedded in the polymer matrix. For the numerical simulation of such a self-healing material, a thermodynamically consistent multiphase model, based on the Theory of Porous Media, is developed in this contribution. The different phases of the model are the solid matrix material with embedded catalysts, the liquid healing agents, the solid healed material and the gas phase, which represents the volume fraction of the micro cracks in the model. For the description of the healing mechanism, a mass exchange between the liquid healing agents and the solid healed material, in consideration of the change of the aggregate state, is introduced, which depends on the local concentration of catalysts in the polymer matrix. The applicability of the developed model is shown by means of numerical test simulations of a tapered double cantilever beam.