Theoretical framework of modeling of ionic EAPs within the Theory of Porous Media

摘要

A thermo-electromechanical formulation for the description of ionic electroactive polymers is derived within the framework of the Theory of Porous Media. The model consists of an electrically charged porous solid saturated with an ionic solution. The saturated porous medium is assumed to be incompressible. Different constituents following different kinematic paths are considered such as solid, fluid, anions, cations and free charges. The electromechanical and the electrodynamic field equations are discussed. Based on the second law of thermodynamics, a consistent model is developed. With respect to the closure problem of the model, the needed constitutive relations and evolution equations are presented.