Surface-driven charge storage behaviors of Kenaf-derived carbon electrodes with hierarchical porous structure for lithium-ion capacitors

摘要

On this work, we prepared the porous activated carbon as cathode of lithium-ion capacitor through two-step fabrication process using kenaf as biomass carbon precursor possible easily scaled-up for industrial production. The biomass-derived porous carbon shows an extremely high specific surface area of 2,719 m(2) g(-1) and relatively applicable pore volume of 1.6 m(3) g(-1) as well as well-developed carbon structure. As a result, it exhibits excellent lithium-ion capacitive performances with specific capacity of similar to 195 mA h g(-1) at a current rate of 0.1 A g(-1), good rate capability at current rates ranging from 0.1 to 4 A g(-1), and outstanding cycling stability in organic electrolyte. These results suggest that the optimization of pore and carbon microstructure of biomass-derived carbon is contributed to outstanding electrochemical performance for improving the energy density of lithium-ion capacitor.