首页> 外文期刊>Applied Surface Science >Preparation and properties of visible light responsive RGO/In_2TiO_5 nanobelts for photocatalytic degradation of organic pollutants
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Preparation and properties of visible light responsive RGO/In_2TiO_5 nanobelts for photocatalytic degradation of organic pollutants

机译:可见光响应性RGO / In_2TiO_5纳米带的制备及其对有机污染物的光催化降解性能

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摘要

Electrospinning and solvothermal methods were used to synthesize RGO/In2TiO5 nanobelts. The prepared samples were characterized with XRD, SEM, UV-vis DRS, N-2 adsorption-desorption isotherms, FT-IR and Raman spectroscopy. The results have shown that the samples presented an orthorhombic structure without any secondary phase, and the morphology was not noticeably changed after coupling RGO. The RGO (1 wt%)/In2TiO5 nanobelts showed the highest photocatalytic activity. After 120 min of simulated sunlight irradiation, the degradation rate of RhB was up to 97.5%. Meanwhile, RGO/In2TiO5 nanobelts showed excellent photocatalytic degradation property for fluoroquinolone antibiotic levofloxacin (LEV). The increased electrons and holes separation, enhanced active sites and improved light acquisition were the reasons for the outstanding photocatalytic performances of the photocatalyst. Moreover, terephthalic acid photoluminescence (TA-PL) experiments confirmed that the hydroxyl radicals (center dot OH) were generated during the photocatalysis processes. The enhanced photocatalytic activity allows RGO/In2TiO5 nanobelts to be a promising candidate to treat antibiotic medical wastewater field in the future.
机译:采用静电纺丝和溶剂热法合成了RGO / In2TiO5纳米带。用XRD,SEM,UV-vis DRS,N-2吸附-解吸等温线,FT-IR和拉曼光谱对制备的样品进行表征。结果表明,样品呈现出正交相结构,没有任何次级相,并且在偶联RGO后其形态没有明显改变。 RGO(1 wt%)/ In2TiO5纳米带显示出最高的光催化活性。在模拟太阳光照射120分钟后,RhB的降解率高达97.5%。同时,RGO / In2TiO5纳米带对氟喹诺酮类抗生素左氧氟沙星(LEV)具有优异的光催化降解性能。电子和空穴间隔的增加,活性位点的增加和光的获取的改善是光催化剂具有出色的光催化性能的原因。此外,对苯二甲酸光致发光(TA-PL)实验证实,在光催化过程中产生了羟基自由基(中心点OH)。增强的光催化活性使RGO / In2TiO5纳米带成为未来治疗抗生素医疗废水领域的有希望的候选者。

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  • 来源
    《Applied Surface Science》 |2019年第15期|547-553|共7页
  • 作者单位

    Yulin Univ, Sch Civil Engn, Yulin 71900, Shaanxi, Peoples R China|Shaanxi Key Lab Ecol Restorat Shanbei Min Area, Yulin 719000, Shaanxi, Peoples R China;

    Jackson State Univ, Dept Chem, Jackson, MS 39217 USA;

    Jackson State Univ, Dept Chem, Jackson, MS 39217 USA;

    Jackson State Univ, Dept Chem, Jackson, MS 39217 USA;

    Jackson State Univ, Dept Chem, Jackson, MS 39217 USA;

    Jackson State Univ, Dept Chem, Jackson, MS 39217 USA;

    Jackson State Univ, Dept Chem, Jackson, MS 39217 USA;

    Jackson State Univ, Dept Chem, Jackson, MS 39217 USA;

    Jackson State Univ, Dept Chem, Jackson, MS 39217 USA;

    Shaanxi Key Lab Ecol Restorat Shanbei Min Area, Yulin 719000, Shaanxi, Peoples R China;

    Xian Univ Technol, Dept Appl Chem, Xian 710048, Shaanxi, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    RGO/In2TiO5; Photocatalysis; Visible light; Degradation;

    机译:RGO / In2TiO5;光催化;可见光;降解;

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