The influence of nonpolar organics adsorption on the electrochemical behaviour of powdered activated carbon electrodes in aqueous electrolytes

摘要

Adsorption and electrochemical studies were carried out on three activated carbon samples first oxidized, then heat-treated under vacuum (at 180, 500 and 900 ℃). The investigations were performed with aqueous electrolyte (Na_2HPO_4 and H_3PO_4) solutions containing selected nonpolar organics (benzene and n-hexane). Adsorption measurements were carried out on solution with a wide range of organics concentration (up to saturation point). Cyclovoltammetric curves of powdered electrodes prepared from the activated carbon samples were recorded for the organics in saturated solutions. The electric double layer capacities of the anodic and cathodic parts were estimated, and the surface anodic and cathodic charge was calculated both in absence and presence of organics in the electrochemical systems. The relative surface charge (in relation to systems without organics) was found to decrease with a reduction in the concentration of surface oxygen-containing groups. Other physicochemical parameters characterizing the degree of surface oxidation (total oxygen concentration, primary water adsorption centres) were also taken into consideration. The correlation between adsorption capacity towards the nonpolar organic compounds (obtained from adsorption isotherms) and change of surface charge was analyzed.