Structure and tribological properties of MoCN-Ag coatings in the temperature range of 25-700℃

摘要

The preparation of hard coatings with low friction coefficient over a wide temperature range is still a challenge for the tribological community. The development of new nanocomposite materials consisting of different metal-ceramic phases, each of which exhibiting self-lubricating characteristics at different temperatures, may help to solve this problem. We report on the structure and tribological properties of MoCN-Ag coatings deposited by magnetron co-sputtering of Mo and C (graphite) targets and simultaneous sputtering of an Ag target either in pure nitrogen or in a gaseous mixture of Ar + N_2. The structure and elemental composition of the coatings were studied by means of X-ray diffraction, scanning and transmission electron microscopy, X-ray photoelectron spectroscopy, energy dispersive spectroscopy, Raman spectroscopy, and glow discharge optical emission spectroscopy. The tribological properties of the coatings against an Al_2O_3 ball were investigated first at discrete temperatures of 25,500, and 700℃, and then during continuous heating in the temperature range of 25-700 ℃ The coating structure and their respective wear tracks were also examined to elucidate their phase transformations during heat treatments. The lowest friction coefficients (<0.4) were observed in the temperature ranges of 25-100℃ and 400-700℃ and can be explained by the presence of a free amorphous carbon phase, which served as a lubricant at low temperatures, and by a positive role of silver and two phases forming at elevated temperatures, molybdenum oxide and silver molybdate, which provided lubrication above 400 ℃. In the temperature range between 100 and 400 ℃, the friction coefficient was relatively high. This problem is to be addressed in future works.